Permeation properties of a graded structure composite ceramic membrane prepared by CVD method

سال انتشار: 1390
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 672

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شناسه ملی سند علمی:

ICHEC07_133

تاریخ نمایه سازی: 25 فروردین 1394

چکیده مقاله:

Permeation properties of a hydrogen permselective ceramic membrane for single gases (H2, CH4, N2 and CO2) have been studied. The membrane was prepared by depositing a thin layer of SiO2 onthe inner side of a tubular modified alumina layer by chemical vapor deposition (CVD) method.The modification process was carried out by coating the macroporous α-alumina substrate with different layers of γ-alumina to obtain a graded structure support. XRD, SEM and EDAX analysis were used to characterize the membrane. Cross-sectional and surface images obtained from SEMshowed that the intermediate layer had a thickness of 2 μm with a median pore size of about 50 nm and the top selective silica layer was uniform and dense with a thickness of about 100 nm. Permeation tests showed that H2 permeation flux reduced from 5*10-5 molm-2s-1pa-1 to 6*10-7 molm-2s-1pa-1 as the CVD deposition time proceeded from 0 to 6 h and H2 selectivities over CH4, N2 and CO2 increased from 2.2, 5.6 and 7.9 to 105, 178 and 446, respectively

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نویسندگان

Ensieh Ganji Babakhani

Research Institue of Petroleum Industry,Tehran,Iran

Mahdi Amanipour

Sharif University of Technology,Tehran,Iran

Aliakbar Safe kordi

Sharif University of Technology,Tehran,Iran

Akbar Zamaniyan

Research Institue of Petroleum Industry,Tehran,Iran

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