Solvothermal synthesis and characterization of a porousnanosizeZr-basedMOFwith high stability

A porous Zr-based MOF was synthesized bysolvothermal method using 1,4-benzenedicarboxylic acid,as an organic linker, and its stability were investigated systematically.Using the solvothermal route with the benefits of both sol-gel and hydrothermal routes, the as-synthesized sample has been characterized by X-ray diffraction,scanning electron microscopy, Fourier transform infraredspectroscopy andBET surface areamethods. The results showed that Zr-MOF was synthesized as crystallites with cube-like shape and the size of~100-150 nm.

کلیدواژه ها:

Metal-organic framework ، Synthesis ، Microporous ، Zirconium ، Benzenedicarboxylic acid