KINETICS OF REACTION BETWEEN DMAD AND MELDRUM’S ACID IN THE PRESENCE OF TRIPHENYLARSINE

سال انتشار: 1395
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 693

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شناسه ملی سند علمی:

TCPCO03_159

تاریخ نمایه سازی: 16 شهریور 1395

چکیده مقاله:

The kinetics and mechanistic investigation of the reaction between dimethyl acetylendicarboxcylate (DMAD) and Meldrum’s acid has been studied in ethanol environment with triphenylarsine as a catalyst using UV/vis spectrophotometry. The reaction followed second order kinetics. In the kinetics study, activation energy and parameters (Ea, ΔHǂ, ΔSǂ and ΔGǂ) were determined. Also, reaction rate is accelerated by increasing the temperature and the dielectric constant of solvent

نویسندگان

F Ghodsi

Department of Chemistry, University of Sistan and Baluchestan,Zahedan, Iran

S.M Habibi-Khorassani

Department of Chemistry, University of Sistan and Baluchestan,Zahedan, Iran

M Shahraki

Department of Chemistry, University of Sistan and Baluchestan,Zahedan, Iran

M Hashemi-Shahri

Department of Chemistry, University of Sistan and Baluchestan,Zahedan, Iran