CIVILICA We Respect the Science
(ناشر تخصصی کنفرانسهای کشور / شماره مجوز انتشارات از وزارت فرهنگ و ارشاد اسلامی: ۸۹۷۱)

Promotion Effect of Fe on Mo/Al2O3 Catalyst for the CAMERE Process

عنوان مقاله: Promotion Effect of Fe on Mo/Al2O3 Catalyst for the CAMERE Process
شناسه ملی مقاله: ICHEC07_348
منتشر شده در هفتمین کنگره ملی مهندسی شیمی در سال 1390
مشخصات نویسندگان مقاله:

Abolfazl Gharibi Kharaji - Petroleum University of Technology, Ahwaz Faculty of Petroleum Engineering, Gas Engineering Department,Ahwaz, Iran,
Ahmad Shariati - Petroleum University of Technology, Ahwaz Faculty of Petroleum Engineering, Gas Engineering Department,Ahwaz, Iran,
Mohammad Ali Takassi - Petroleum University of Technology, Ahwaz Faculty of Petroleum Engineering, Science Department, Ahwaz,Iran,

خلاصه مقاله:
Reverse Water Gas Shift (RWGS) reaction is one of the main reactions that can be used to reduce greenhouse gases emissions. Through this reaction CO2 is converted to CO to produce beneficialchemicals such as methanol. In this paper Mo/Al2O3 catalyst was prepared and then promoted withFe ions through co-impregnation method to produce Fe-Mo/Al2O3 catalyst. XRD tests were taken to determine the structure of the catalysts. Activity, selectivity and stability of both catalysts were investigated in a batch reactor and the results indicate that addition of Fe promoter to Mo/Al2O3catalyst increased its activity and CO selectivity. Fe-Mo/Al2O3 showed acceptable catalytic stability during RWGS reaction. As a whole, Fe-Mo/Al2O3 can be a suitable candidate for RWGS reaction in CAMERE (carbon dioxide hydrogenation to form methanol via a reverse-water-gasshift reaction) process.

کلمات کلیدی:
RWGS reaction, Fe-Mo ، Al2O3 catalyst, Methanol process, greenhouse gases

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/341099/