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The study of temperature effect on the refractive index of mixing (Cyclohexanone (1) +N,N-Ndimethylacetamide(2) +N,N-diethylethanolamine (3) . An experimental and theoretical study

عنوان مقاله: The study of temperature effect on the refractive index of mixing (Cyclohexanone (1) +N,N-Ndimethylacetamide(2) +N,N-diethylethanolamine (3) . An experimental and theoretical study
شناسه ملی مقاله: ISPTC12_073
منتشر شده در دوازدهمین سمینار شیمی فیزیک ایران در سال 1388
مشخصات نویسندگان مقاله:

H. Iloukhani - Faculty of Chemistry, University of Bu Ali Sina, Hamadan, Iran
M. R. Sameti - Departemnt of Chemistry, Faculty of Science , Malayer University, Malayer, Iran
M Rakhshi - Faculty of Chemistry, University of Bu Ali Sina, Hamadan, Iran

خلاصه مقاله:
Refractive index for binary and ternary mixtures {cyclohexanone(1) +n,n-dimethylacetamide(2) + n,ndiethylethanolamine (3) have been determined over the full range of compositions over the temperature range (298.15 to 318.15K) and the ambient pressure 81.5 kPa , using a thermostated Abbe´refractometer. Refractive index deviations are negative over the mole fraction range for all binary and ternary mixtures and increase with increasing temperatures from (298.15 to 318.15) K.This means that the interaction of like moleculars is stronger than the unlike molecular intractions. The refractive index deviations of binary mixtures have been fitted to the Redlich−Kister and ternary mixture has been fitted to the Cibulka, Jasinski and Malanowski ,Singe et al, Calvo et al. Lorentz–Lorenz , Dale–Gladstone and Eykman equations to determine the coefficients. The experimental data of the condtituent binary and ternary mixtures are analysed to discuss the nature and strength of intermolecular intractions in these mixtures.

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/292230/