Comparasion of copolymerization and terpolymerization with (Ind)2ZrCl2 metallocene catalyst
عنوان مقاله: Comparasion of copolymerization and terpolymerization with (Ind)2ZrCl2 metallocene catalyst
شناسه ملی مقاله: ICHEC07_519
منتشر شده در هفتمین کنگره ملی مهندسی شیمی در سال 1390
شناسه ملی مقاله: ICHEC07_519
منتشر شده در هفتمین کنگره ملی مهندسی شیمی در سال 1390
مشخصات نویسندگان مقاله:
s Ahmadjo - Faculty of Polymerization Engineering, Iran Polymer and Petrochemical Institute, P. O. Box: ۱۴۹۶۵/۱۱۵,Tehran, Iran
h Arabi - Faculty of Polymerization Engineering, Iran Polymer and Petrochemical Institute, P. O. Box: ۱۴۹۶۵/۱۱۵,Tehran, Iran
m Nekoomanesh - Faculty of Polymerization Engineering, Iran Polymer and Petrochemical Institute, P. O. Box: ۱۴۹۶۵/۱۱۵,Tehran, Iran
g.h zohuri - Chemistry Group, Department of Science, Ferdowsi University of Mashhad, Mashhad-۹۱۷۷۵, Iran
خلاصه مقاله:
s Ahmadjo - Faculty of Polymerization Engineering, Iran Polymer and Petrochemical Institute, P. O. Box: ۱۴۹۶۵/۱۱۵,Tehran, Iran
h Arabi - Faculty of Polymerization Engineering, Iran Polymer and Petrochemical Institute, P. O. Box: ۱۴۹۶۵/۱۱۵,Tehran, Iran
m Nekoomanesh - Faculty of Polymerization Engineering, Iran Polymer and Petrochemical Institute, P. O. Box: ۱۴۹۶۵/۱۱۵,Tehran, Iran
g.h zohuri - Chemistry Group, Department of Science, Ferdowsi University of Mashhad, Mashhad-۹۱۷۷۵, Iran
Bis(indeneyl)zirconium dichloride, (Ind)2ZrCl2, catalyst was synthesized and used for copolymerization of ethylene and propylene (EPR) and, terpolymerization of ethylene propylene and 5-ethyldiene-2-norbornene (ENB). Methylaluminoxane (MAO) was used as cocatalyst. Activity of The catalyst was higher for the copolymerization of ethylene and propylene (EPR) than ethylene propylene and diene monomer terpolymeization(EPDM). The effect of [Al]/[Zr] ratio, temperature, relative pressure of E/P and the ENBconcentration on the polymerization behavior were studied.
کلمات کلیدی: Metallocene, copolymerization, terpolymerization, EPR, EPDM
صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/341269/