Investigating the influence of copper (I) thiocyanate as a hole transport layer in efficiency of methylammonium lead iodide perovskite solar cells
محل انتشار: بیست و یکمین کنفرانس شیمی فیزیک انجمن شیمی ایران
سال انتشار: 1397
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 318
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شناسه ملی سند علمی:
ISPTC21_249
تاریخ نمایه سازی: 30 دی 1397
چکیده مقاله:
In the past few years, organic-inorganic perovskite solar cells have been improveddrastically in terms of solar to electric power conversion efficiency (PCE) and stability [1]. Thehole-transport material (HTM) is an important part of cell which facilitates the separation ofelectron-hole pairs [2]. In this research, the copper (I) thiocyanate (CuSCN) was synthesized andused as an efficient and cheap hole transport layer in methylammonium lead iodide (MAPbI3)perovskite solar cell. The FTO glass is used as anode. Initially, the thin layer of titanium oxideas a blocking layer is deposited on the FTO substrate using the spin-coating method (2000 rpm,20 s) and annealed at 450 ℃ for 30 min. Then, a layer of mesoporous titanium oxide preparedfrom commercial TiO2 (P25, Degussa) was deposited on the previous layer. A thin layer ofMAPbI3 was spin coated on the titanium oxide mesoporous layer as active layer. The synthesizedCuSCN as a HTM was deposited on perovskite layer by spin-coating method (2000 rpm, 20 s)and dried at 120 ℃ for 15 min. Finally, the graphite powder was used as cathode. The I-V curveswere recorded in -1-1 V under dark and illumination of solar light by Solar simulator (AM1.5).The open circuit voltage (VOC) of MAPbI3 solar cell without HTM layer was obtained 670 mV.In the presence of CuSCN, the VOC and other photovoltaic parameters were increased indicatingthe improvement of lead based perovskite solar cell in the presence of CuSCN as an efficient andcheap hole transport layer.
کلیدواژه ها:
نویسندگان
Ahmad Samadifar
Department of Physical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran
Mohamad Ebadi
Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran
Mir Ghasem Hosseini
Department of Physical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran
Darioush Salari
Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran