Electrochemical oxidation of catechol and 4-methylcatechol in the presence of p-toluenesulfinic acid by cyclic voltammograms : application to electrosynthesis
محل انتشار: همایش منطقه ای شیمی
سال انتشار: 1389
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 364
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شناسه ملی سند علمی:
MIAUCHEMISTRY01_156
تاریخ نمایه سازی: 18 اسفند 1397
چکیده مقاله:
Electrochemical oxidation of catechol (1a) and 4-methylcatechol (1b) in the presence of p-toluenesulfinic acid as a nucleophile has been studied in an aqueous solution using cyclic voltammetry and controlled potential coulometry[1]. The results indicate that compounds 1a and 1b react with I, and 4 reacts with I via a Michael addition reaction leading to the sulfones 3a,3b respectively. Products were obtained in good yield and purity.The mechanism of oxidation was deduced from voltammetric data and by coulometry at controlled potential. The products have been characterized after purification by IR, 1H-NMR, and elemental analysis [2,3].
نویسندگان
V. Mahboobi
Sama College, Islamic Azad University,Khoy Branch, Khoy, Iran
M.J. Abolhassanugly
Sama College, Islamic Azad University,Khoy Branch, Khoy, Iran