Discrete Relaxation Spectrum and K-BKZ Constitutive Equation for PVC, NBR and Their Blends
محل انتشار: هشتمین کنگره ملی مهندسی شیمی ایران
سال انتشار: 1382
نوع سند: مقاله کنفرانسی
زبان: انگلیسی
مشاهده: 2,543
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شناسه ملی سند علمی:
NICEC08_008
تاریخ نمایه سازی: 8 اسفند 1386
چکیده مقاله:
Frequency sweep experiments were performed on poly(vinyl chloride) (PVC) and acrylonitrile butadiene rubber (NBR) as well as their miscible blends; i.e. PVC/NBR by mechanical EOHQGLQJ DW C o . In order to investigate the validity of time temperature superposition (TTS) principle, curves of loss angle ) (d
versus the logarithm of absolute value of complex modulus, *) log( G , have been plotted. It has been shown that the TTS principle is not valid for the above-mentioned polymer materials and therefore, they are not t hermorheologically simple. Meanwhile, master curves of PVC, NBR and PVC/NBR OHQG ZHUH REWDLQHG approximately. Using a nonlinear regression method, discrete relaxation spectra have been determined for 39& 1 %5 DQG 39& 1 %5 7R VWXG non-linear viscoelasticity behavior, the
experiments of steady shear, start up steady shear and step strain have been carried out. The damping function was determined by the step strain experiments. Using K-BKZ equation, the shear viscosity and the shear stress growth function were calculated from the discrete relaxation spectra and the damping function, and then compared to experimental data. The K-BKZ constitutive equation provides very good prediction over the entire range of experimental results, particularly; it predicts the main features of
the experimental data.
کلیدواژه ها:
rheology ، poly (vinyl chloride) ، acrylonitrile butadiene rubber ، time temperature superposition ، miscible blend ، shear viscosity ، KBKZ constitutive equation
نویسندگان
Ali Haghtalab
Department of Chemical Engineering, Tarbiat Tehran, Iran
Gholamhossein Sodeifian
Department of Chemical Engineering, Tarbiat Tehran, Iran