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گواهی نمایه سازی مقاله Effect of Ultrasonic Treatment on the Gel Formation of MnSAPO-34 Catalysts in MTO Process

عنوان مقاله: Effect of Ultrasonic Treatment on the Gel Formation of MnSAPO-34 Catalysts in MTO Process
شناسه (COI) مقاله: ICHEC07_342
منتشر شده در هفتمین کنگره ملی مهندسی شیمی در سال ۱۳۹۰
مشخصات نویسندگان مقاله:

Bahman Khabiri - School of Chemical Engineering, Iran University of Science & Technology, Tehran, Iran
Mehdi Alavi - School of Chemical Engineering, Iran University of Science & Technology, Tehran, Iran
Mohammad Haghighi - Reactor & Catalysis Research Center, Sahand New Town, Tabriz, Iran
Mojtaba Charghand - Reactor & Catalysis Research Center, Sahand New Town, Tabriz, Iran
Ghasem Kasaeian - School of Chemical Engineering, Iran University of Science & Technology, Tehran, Iran

خلاصه مقاله:
In order to synthesize the MnSAPO-34 crystal with a pure CHA structure having a uniform size and desired catalytic activity, factors having influence on the crystallization at gel preparation should be considered. In this work Diethylamine and morpholine were used as the organic templates. A perfectly homogeneous gel was obtained by ultrasonic wave treatment before hydrothermal treatment. The results showed that ultrasonic-wave treatment was effective in makingparticle size smaller and in narrowing the size distribution for MnSAPO-34(DEA). In addition, a uniform distribution was obtained with excelent morphology was obtained for MnSAPO-34(Mor) in compared to the one without ultrasonic treatment. Ultrasonic treated MnSAPO-34 catalysts showed similar activity and product distribution with a yield of 84% in the MTO reaction at 400℃.

کلمات کلیدی:
Ultrasound Waves, Acidic Zeotype Catalysts, MnSAPO-34, MTO Process

صفحه اختصاصی مقاله و دریافت فایل کامل: https://www.civilica.com/Paper-ICHEC07-ICHEC07_342.html