Fabrication and Characterization of Poly Vinyl Alcohol/ Poly Vinyl Pyrrolidone/MnTiO Nanocomposite Membranes for PEM Fuel Cells
عنوان مقاله: Fabrication and Characterization of Poly Vinyl Alcohol/ Poly Vinyl Pyrrolidone/MnTiO Nanocomposite Membranes for PEM Fuel Cells
شناسه ملی مقاله: JR_IJEE-4-2_002
منتشر شده در شماره 2 دوره 4 فصل 2012 در سال 1391
شناسه ملی مقاله: JR_IJEE-4-2_002
منتشر شده در شماره 2 دوره 4 فصل 2012 در سال 1391
مشخصات نویسندگان مقاله:
Abdol Mohammad Attaran - Department of Chemistry, Payame Noor University, Delijan, I.R. Iran
Khadijeh hooshyari - Department of Chemistry, Amirkabir University of Technology, Tehran, I.R. Iran
Mehran Javanbakht - Department of Chemistry, Amirkabir University of Technology, Tehran, I.R. Iran
Morteza Enhessari - Department of Chemistry, Islamic Azad University, Naragh Branch, Naragh, I.R.Iran
خلاصه مقاله:
Abdol Mohammad Attaran - Department of Chemistry, Payame Noor University, Delijan, I.R. Iran
Khadijeh hooshyari - Department of Chemistry, Amirkabir University of Technology, Tehran, I.R. Iran
Mehran Javanbakht - Department of Chemistry, Amirkabir University of Technology, Tehran, I.R. Iran
Morteza Enhessari - Department of Chemistry, Islamic Azad University, Naragh Branch, Naragh, I.R.Iran
PVA (poly vinyl alcohol)-MnTiO (PM) and PVA-PVP (poly 3 vinyl pyrrolidone)-MnTiO3 (PPM) nanocomposite membranes have been prepared with solutions casting method. Glutaraldehyde (GA) was usedas cross linking agent. The results showed that the proton conductivity and water uptake of the nanocompositemembranes due to hydrophilic nature of MnTiO3 nanoparticles were higher than that of the PVA membrane.PPM membranes containing 5 wt. % of MnTiO3nanoparticles and PVA:PVP, 80:20, demonstrated higher thermal stability, water uptake (310%) and proton conductivity (2.1 ×10 2 S/cm) than PM membranes, due to hydrophiliceffect of PVP, which can made strong hydrogen-bonding, intense intra-molecular interaction and reduce the crystallinity of the PVA polymer
کلمات کلیدی: PEM fuel cells/ Poly vinyl alcohol/ Poly vinyl pyrrolidone/ Nanocomposite membrans/ Proton conductivity
صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/251957/