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Supported iron oxide nanoparticles: Recoverable and efficient catalyst for direct oxidative amide synthesis under solvent-free conditions

عنوان مقاله: Supported iron oxide nanoparticles: Recoverable and efficient catalyst for direct oxidative amide synthesis under solvent-free conditions
شناسه ملی مقاله: CHCONF01_064
منتشر شده در کنفرانس بین المللی یافته های نوین پژوهشی در شیمی و مهندسی شیمی در سال 1394
مشخصات نویسندگان مقاله:

Fatemeh Rajabi - Department of Science, Payame Noor University, P. O. Box: ۱۹۳۹۵-۴۶۹۷, Tehran, Iran

خلاصه مقاله:
The use of a recoverably supported iron oxide on SBA-15 support (Fe@SBA-15) as a highly efficient catalyst for the oxidative amidation of economic and readily available aldehydes with primary and secondary amines to their corresponding amides was performed under solvent-free conditions using aqueous hydrogen peroxide as benign oxidant. The supported nanocatalyst was proved to be highly active and reusable under the investigated reaction conditions and could be easily recovered from the reaction mixture and reused at least ten successive runs without any significant loss in activity and no metal leaching was observed during this course.

کلمات کلیدی:
supported iron oxide, SBA-15, amidation, aldehydes

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/412602/