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Facile synthesis of Graphene aerogel/Co3O4 nanocomposite by mild chemical reduction method

عنوان مقاله: Facile synthesis of Graphene aerogel/Co3O4 nanocomposite by mild chemical reduction method
شناسه ملی مقاله: IMES12_121
منتشر شده در هفتمین کنفرانس بین المللی مهندسی مواد و متالورژی و دوازدهمین همایش ملی مشترک انجمن مهندسی متالورژی و مواد ایران و انجمن ریخته گری ایران در سال 1397
مشخصات نویسندگان مقاله:

Arash Ghazitabar - Department of Mining and Metallurgical Engineering, Amirkabir University of Technology, Hafez ave., Tehran, Iran
Malek Naderi - Department of Mining and Metallurgical Engineering, Amirkabir University of Technology, Hafez ave., Tehran, Iran
Davoud Haghshenas Fatemehsari - Department of Mining and Metallurgical Engineering, Amirkabir University of Technology, Hafez ave., Tehran, Iran

خلاصه مقاله:
Production of metallic oxide/graphene aerogel composite system is great importance regarding their super electrochemical and adsorption characteristics. In the present work, Cobalt oxide/graphene aerogel nanocomposite was synthesized via mild reduction in order to the facile, cost effective and environmentally friendly route. L-Ascorbic acid (LAA) was used as both the reducing agent and cross-linker. The formation of Co3O4 was confirmed by X-Ray diffraction (XRD) analysis. According to microscopic images, the spherical Co3O4 nanoparticles were randomly distributed over the graphene sheets (the size distribution of 8-10 nm). In addition, the BET surface area and the pore volume of composite were estimated 215 (m2.g-1) and 1.22 (cm3.g-1), respectively. Moreover, the bulk density was 19 (mg.cm-3) and the load bearing limit of composite was higher than 2000 times of its own weight. The addition of Co3O4 nanoparticles (in ratio of Co3O4: graphene 1:50) improve specific capacitance of graphene aerogel electrode materials, reaching about 400 F.g-1, suggesting great potential for supercapacitor.

کلمات کلیدی:
Graphene aerogel, Hummer’s method, mild chemical reduction, L-ascorbic acid, supercapacitor

صفحه اختصاصی مقاله و دریافت فایل کامل: https://civilica.com/doc/841879/