Stress Corrosion Cracking Detection of Sensitized Stainless Steel ۳۰۴ in Chloride Media by Using Electrochemical Impedance Spectroscopy (EIS)

Electrochemical impedance spectroscopy (EIS) was used to detect stress corrosion cracking (SCC) in stainless steel ۳۰۴ alloy exposed to an aqueous environment at ۱۲۰ °C. Stainless steel ۳۰۴ alloy as u-bend was tested in the solution that contains ۴۰ weight percent of magnesium chloride. U-bended samples were prepared according to ASTM G۳۰. EIS measurements were always performed simultaneously on u-bend samples under stress and non-stress conditions. The results indicate that changes in phase shift versus time could be related to the stress corrosion cracking process. Stress corrosion cracking is detectable at a frequency of ۲۳.۹۵ Hz. EIS measurement can be used for SCC monitoring in u-bend samples. Finally, analysis of the fracture surface by using metallographic and SEM techniques confirmed the EIS results.

کلیدواژه ها:

Stress Corrosion Cracking ، Stainless Steel ۳۰۴ ، U-Bend ، Monitoring ، EIS