A new synthetic method of nano porous {[{Co(H2O)2}(m-bpp)2].2(H2O).2(NO3).bpp} .

Room temperature reaction afforded a porous compound by using Co(NO3)2.4H2O and 1,3-bis(4-pyridyl)propane (bpp) which had been synthesized in hydrothermal condition. This structure has one-dimensional linear ribbon like chain that makes porous compound about 1.1 nm diameters through each two cobalt metals and free nitrate ions and free bpp in the regions between the chains. two 4, 4’-trimethylendipyridine as bridging ligands together with two H2O molecules coordinate to the cobalt(II) ions completing octahedral geometry around. The Structure of the title compound was examined by single crystal X-Ray technique

کلیدواژه ها:

Coordination polymer ، MOF ، one-dimensional Chain ، 1 ، 3-bis(4-pyridyl)propane (bpp) ، X-Ray Diffraction